BIS(DIMETHYLGLYOXIMATO-N,N')(ETHYL)-(TRIPHENYLPHOSPHINE)RHODIUM(III)

被引：16

作者：

KETTMANN, V

DUNAJJURCO, M

STEINBORN, D

LUDWIG, M

机构：

[1] SLOVAK UNIV TECHNOL BRATISLAVA, FAC CHEM TECHNOL, DEPT INORGAN CHEM, BRATISLAVA 81237, SLOVAKIA

[2] MARTIN LUTHER UNIV HALLE WITTENBERG, INST ANORGAN CHEM, O-4200 MERSEBURG, GERMANY

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1994年 / 50卷

关键词：

D O I：

10.1107/S0108270194000107

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The structure of [Rh(C4H7N2O2)(2)(C2H5)(C18H15P)] consists of discrete complex molecules in which the Rh atom displays distorted octahedral coordination; the two dimethylglyoxime ligands lie in the equatorial plane and the ethyl and triphenylphosphine groups occupy the axial positions. The Rh atom is displaced by 0.130 (1) Angstrom from the mean plane through the four oxime N donor atoms in the direction of the P atom. The Rh-N distances range from 1.903 (6) to 1.993 (6) Angstrom, while the axial Rh-P and Rh-C distances are 2.461 (2) and 2.064 (7) Angstrom, respectively. Comparison of the results with those obtained previously for analogous compounds containing the axial fragment Ph(3)P-Rh-X indicates that the trans influence of X is determined by its sigma-donor power.

引用

页码：1239 / 1241

页数：3

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