CATALYTIC ACTIVITY OF PEG-QUAT PHASE-TRANSFER CATALYSTS IN DEHYDROHALOGENATION REACTIONS

被引:18
|
作者
GRINBERG, S
SHAUBI, E
机构
[1] The Institutes for Applied Research, Ben-Gurion University of the Negev, Beer-Sheva, 84110
关键词
D O I
10.1016/S0040-4020(01)87094-0
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
New polyethylene glycol ammonium and phosphonium salts (PEG-quat) phase-transfer catalysts were synthesized and their catalytic activity was studied in a dehydrohalogenation liquid-liquid phase-transfer system. The catalytic activity of the PEG-quat catalyst depended on the nature of the quaternary salt, the most effective compounds being those in which only one hydroxyl group is replaced by the quaternary function.
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页码:2895 / 2902
页数:8
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