CATALYTIC ACTIVITY OF PEG-QUAT PHASE-TRANSFER CATALYSTS IN DEHYDROHALOGENATION REACTIONS

被引:18
作者
GRINBERG, S
SHAUBI, E
机构
[1] The Institutes for Applied Research, Ben-Gurion University of the Negev, Beer-Sheva, 84110
关键词
D O I
10.1016/S0040-4020(01)87094-0
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
New polyethylene glycol ammonium and phosphonium salts (PEG-quat) phase-transfer catalysts were synthesized and their catalytic activity was studied in a dehydrohalogenation liquid-liquid phase-transfer system. The catalytic activity of the PEG-quat catalyst depended on the nature of the quaternary salt, the most effective compounds being those in which only one hydroxyl group is replaced by the quaternary function.
引用
收藏
页码:2895 / 2902
页数:8
相关论文
共 12 条
[1]  
BALASUBRAMANIAN D, 1979, TETRAHEDRON LETT, P3543
[2]  
BAYER E, 1982, POLYM BULL, V8, P585
[3]  
BUCKMANN AF, 1981, MAKROMOL CHEM, V182, P1379
[4]  
DAREN SLJ, 1980, Patent No. 4202453
[5]   HYDROXIDE ION INITIATED REACTIONS UNDER PHASE-TRANSFER CATALYSIS CONDITIONS .9. DEHYDROHALOGENATION OF (HALOETHYL)BENZENES BY QUATERNARY AMMONIUM-SALTS [J].
HALPERN, M ;
ZAHALKA, HA ;
SASSON, Y ;
RABINOVITZ, M .
JOURNAL OF ORGANIC CHEMISTRY, 1985, 50 (25) :5088-5092
[6]  
JACKISCH PF, 1983, Patent No. 4423262
[8]   POLY(ETHYLENE-GLYCOLS) ARE EXTRAORDINARY CATALYSTS IN LIQUID-LIQUID 2-PHASE DEHYDROHALOGENATION [J].
KIMURA, Y ;
REGEN, SL .
JOURNAL OF ORGANIC CHEMISTRY, 1982, 47 (12) :2493-2494
[9]   OXIDATION OF HYDROCARBONS .8. USE OF DIMETHYL POLYETHYLENE-GLYCOL AS A PHASE TRANSFER AGENT FOR OXIDATION OF ALKENES BY POTASSIUM-PERMANGANATE [J].
LEE, DG ;
CHANG, VS .
JOURNAL OF ORGANIC CHEMISTRY, 1978, 43 (08) :1532-1536
[10]   MODIFIED CROWN ETHER CATALYSTS .3. STRUCTURAL PARAMETERS AFFECTING PHASE-TRANSFER CATALYSIS BY CROWN ETHERS AND A COMPARISON OF THE EFFECTIVENESS OF CROWN ETHERS TO THAT OF OTHER PHASE-TRANSFER CATALYSTS [J].
STOTT, PE ;
BRADSHAW, JS ;
PARISH, WW .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (14) :4810-4815