CIRCULAR-DICHROISM AND MAGNETIC CIRCULAR-DICHROISM SPECTRA OF PHENYLALANINE AND ITS DERIVATIVES

被引：4
作者：
KOMIYAMA, T
MIWA, M
机构：
[1] Department of Industrial Chemistry, Faculty of Engineering, Seikei University Musashino-shi, Tokyo ISO
来源：
CHEMICAL PHYSICS LETTERS | 1979年 / 65卷 / 01期
关键词：
D O I：
10.1016/0009-2614(79)80143-8
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Circular dichroism (CD) and magnetic circular dichroism (MCD) spectra of phenylalanine and its derivatives have been observed in aqueous or EPA solution and in PVA film at room temperature and 77 K. MCD spectra corrected for the intrinsic CD have been compared with the intrinsic CD spectra under reversal of the magnetic field direction. MCD spectra show remarkable pH dependence at pH values higher than 9 in aqueous solution. The expected inversion symmetry under reversal of the magnetic field is not found for MCD spectra of phenylalanine and its derivatives. © 1979.
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页码：136 / 139
页数：4
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