SYNTHESIS, REACTIVITY, AND MOLECULAR-STRUCTURE OF [(N(CH2CH2O)3SI-C6H5)W(CO)3]

被引：8

作者：

LEE, JS

CHUNG, YK

WHANG, DM

KIM, KM

机构：

[1] SEOUL NATL UNIV,COLL NAT SCI,DEPT CHEM,SEOUL 151742,SOUTH KOREA

[2] POHANG INST SCI & TECHNOL,DEPT CHEM,KYUNG BUK 790600,SOUTH KOREA

[3] POHANG INST SCI & TECHNOL,CTR BIOFUNCT MOLEC,KYUNG BUK 790600,SOUTH KOREA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 445卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(93)80185-E

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of phenylsilatrane with W(CO)6 gives the compound [C6H5Si(OCH2CH2)3N]W(CO)3 (1) in high yield. Compound 1 has been characterized by elemental analysis, IR, H-1 NMR, and X-ray diffraction methods. Compound 1 crystallizes in the orthorhombic space group Pbca, with a = 22.258(5) angstrom, b = 12.237(1) angstrom, c = 12.313(3) angstrom, and Z = 8. Metallation of 1 by n-butyllithium in THF and subsequent treatment of the lithium derivatives with electrophile have been performed.

引用

页码：49 / 54

页数：6

共 15 条

[1] CONFORMATIONAL EFFECTS OF NUCLEOPHILIC AND ELECTROPHILIC ATTACK ON (ARENE)CHROMIUM TRICARBONYL COMPLEXES
ALBRIGHT, TA
CARPENTER, BK
[J]. INORGANIC CHEMISTRY, 1980, 19 (10) : 3092 - 3097
[2] [Anonymous], 1974, INT TABLES XRAY CRYS, VIV, p[99, 149]
[3] CARD RJ, 1980, J ORG CHEM, V46, P2560
[4] CDALDORAZZO F, 1984, J CHEM SOC DA, P1059
[5] INTERRUPTION OF CONJUGATION IN POLYENES BOUND TO TRANSITION-METAL FRAGMENTS
CHINN, JW
HALL, MB
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (15) : 4930 - 4941
[6] SYNTHESIS, CHARACTERIZATION, AND REACTIVITY OF A CHROMIUM TRICARBONYL COMPLEX OF PHENYLSILATRANE - MOLECULAR-STRUCTURE OF [C6H5SI(OCH2CH2)3N]CR(CO)3
CHUNG, TM
LEE, YA
CHUNG, YK
JUNG, IN
[J]. ORGANOMETALLICS, 1990, 9 (06) : 1976 - 1979
[7] FISCHER EO, 1958, Z NATURFORSCH PT B, V13, P458
[8] META FUNCTIONALIZATION OF ANILINES AND PHENOL
FUKUI, M
IKEDA, T
OISHI, T
[J]. TETRAHEDRON LETTERS, 1982, 23 (15) : 1605 - 1608
[9] SYNTHESIS AND STRUCTURE-ANALYSIS OF [(TBUC6H5)MN(CO)3]CLO4 AND ITS REACTION WITH SOME NUCLEOPHILES
JEONG, EH
CHUNG, YK
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1992, 434 (02) : 225 - 233
[10] SYNTHESIS OF TRICARBONYL-ETA-5-CYCLOHEXADIENYLTUNGSTENATE AND TRICARBONYL-ETA-5-CYCLOHEXADIENYLMETHYLTUNGSTEN
KREITER, CG
HELLMANN, T
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 405 (01) : C6 - C10

← 1 2 →