NOVEL C-C BOND FORMATION REACTIONS MEDIATED BY (OXAALLYL)MOLYBDENUM COMPLEXES

被引：7
作者：
FALLER, JW
MA, YN
机构：
[1] Department of Chemistry, Yale University, Connecticut 06511-8118, New Haven
来源：
ORGANOMETALLICS | 1993年 / 12卷 / 05期
关键词：
D O I：
10.1021/om00029a056
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Treatment Of MO(CO)3(NCMe)3 with a-chloroacetophenone yields intermediate aldol condensation products that can be trapped as stable cyclopentadienyl complexes. The reactions are highly stereoselective and give predominantly one isomer of each product. CpMo(CO)2[eta3-CH2C(Ph)=CH(COPh)] and CPMO(CO)2[eta3-CH2C(Ph)CHC(Ph)=CH(COPh)] were isolated and characterized by X-ray crystallography.
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页码：1927 / 1930
页数：4
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