INFRARED, RAMAN, AND COHERENT ANTI-STOKES-RAMAN SPECTROSCOPY OF THE HYDROGEN-DEUTERIUM ISOTOPOMERS OF NITROMETHANE

被引：47
|
作者：
HILL, JR [1 ]
MOORE, DS [1 ]
SCHMIDT, SC [1 ]
STORM, CB [1 ]
机构：
[1] UNIV CALIF LOS ALAMOS SCI LAB,LOS ALAMOS,NM 87545
来源：
JOURNAL OF PHYSICAL CHEMISTRY | 1991年 / 95卷 / 08期
关键词：
D O I：
10.1021/j100161a019
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The vibrational spectroscopy of the four hydrogen/deuterium isotopomers of nitromethane was investigated. Infrared, Raman, and coherent anti-Stokes Raman spectroscopy (CARS) of the isotopomers were used to determine vibrational frequencies for each isotopomer. Results for the d0, d2, and d3 isotopomers agree well with literature values. Gas- and liquid-phase spectra for the d1 isotopomer are presented, and the measured vibrational frequencies compare well with a theoretical prediction. In addition, high-resolution Raman spectra of the CN stretch mode were used to analyze the elements of the anharmonic coupling matrix involving this mode. Finally, the relative differential Raman scattering cross section of the CN stretch mode of each isotopomer was determined.
引用
收藏
页码：3037 / 3044
页数：8
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