PRODUCTION OF N, H, AND NH ACTIVE SPECIES IN N-2-H(2) DC FLOWING DISCHARGES

被引:59
作者
AMORIM, J
BARAVIAN, G
RICARD, A
机构
[1] Laboratoire de Physique des Gaz et des Plasmas, Université Paris XI, Orsay Cedex
关键词
LASER-INDUCED FLUORESCENCE; FLOWING DC DISCHARGE; N-2-H-2; MIXTURE;
D O I
10.1007/BF01447069
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Densities of N, H, and NH active species have been detected by laser-induced fluorescence (LIF) in N-2-xH(2) dc flowing discharges. A peak value of N atom densities for x=0.2-0.5% and a plateau value of H atom densities between x = 1% and 90% in post-discharge conditions (Delta t similar to 0.05 sec, p = 2 torr) has been found. Comparison between LIF measurements of N atoms and the trend of the N-2(B, upsilon = 11) population shows that the emission from this state can be used for monitoring N atoms. The NH radical has only been detected inside the discharge region.
引用
收藏
页码:721 / 731
页数:11
相关论文
共 18 条
[1]   2-PHOTON LASER-INDUCED FLUORESCENCE AND AMPLIFIED SPONTANEOUS EMISSION ATOM CONCENTRATION MEASUREMENTS IN O(2) AND H(2) DISCHARGES [J].
AMORIM, J ;
BARAVIAN, G ;
TOUZEAU, M ;
JOLLY, J .
JOURNAL OF APPLIED PHYSICS, 1994, 76 (03) :1487-1493
[2]  
AMORIM J, 1993, 11TH P INT S PLASM C, P1511
[3]  
CAPITELLI M, 1986, TOP CURR PHYS, V56, P5
[4]  
CERNOGORA G, 1981, THESIS ORSAY
[6]   TIME-RESOLVED LIF SPECTROSCOPY ON N-2(A) METASTABLE IN A HE/N-2, PULSED RF DISCHARGE [J].
DEBENEDICTIS, S ;
DILECCE, G ;
SIMEK, M .
CHEMICAL PHYSICS, 1993, 178 (1-3) :547-560
[7]   NH (X3-SIGMA-,V=1-3) FORMATION AND VIBRATIONAL-RELAXATION IN ELECTRON-IRRADIATED AR/N2/H2 MIXTURES [J].
DODD, JA ;
LIPSON, SJ ;
FLANAGAN, DJ ;
BLUMBERG, WAM ;
PERSON, JC ;
GREEN, BD .
JOURNAL OF CHEMICAL PHYSICS, 1991, 94 (06) :4301-4310
[8]   NONEQUILIBRIUM ELECTRONIC AND VIBRATIONAL KINETICS IN H-2-N-2 AND H-2 DISCHARGES [J].
GARSCADDEN, A ;
NAGPAL, R .
PLASMA SOURCES SCIENCE & TECHNOLOGY, 1995, 4 (02) :268-280
[9]  
Golubovskii Yu. B., 1984, Soviet Physics - Technical Physics, V29, P727
[10]  
LEBRUN JP, 1972, MEM ETUD SCI REV MET, V69, P727