REACTIONS OF TRIETHYLGERMYLPENTAFLUOROBENZENE WITH SOME ELECTROPHILIC AGENTS

被引：3
|
作者：
BARDIN, VV
ROGOZA, LN
FURIN, GG
机构：
[1] Institute of Organic Chemistry, Novosibirsk
来源：
HETEROATOM CHEMISTRY | 1994年 / 5卷 / 01期
关键词：
D O I：
10.1002/hc.520050115
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Triethylgermylpentafluorobenzene C6F5GeEt3 reacts with CF3SO3H, HSO3Cl, Me3SiOSO2Cl, chlorine, bromine, Cl2/AlCl3, or Br2/AlBr3 with cleavage of the C(aryl)-Ge bond. Cesium fluoride promotes electrophilic degermylation of C6F5GeEt3, possibly via the intermediate formation of a tetraorganylfluorogermanate.
引用
收藏
页码：91 / 95
页数：5
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