REACTIONS OF TRIETHYLGERMYLPENTAFLUOROBENZENE WITH SOME ELECTROPHILIC AGENTS

被引：3

作者：

BARDIN, VV

ROGOZA, LN

FURIN, GG

机构：

[1] Institute of Organic Chemistry, Novosibirsk

来源：

HETEROATOM CHEMISTRY | 1994年 / 5卷 / 01期

关键词：

D O I：

10.1002/hc.520050115

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Triethylgermylpentafluorobenzene C6F5GeEt3 reacts with CF3SO3H, HSO3Cl, Me3SiOSO2Cl, chlorine, bromine, Cl2/AlCl3, or Br2/AlBr3 with cleavage of the C(aryl)-Ge bond. Cesium fluoride promotes electrophilic degermylation of C6F5GeEt3, possibly via the intermediate formation of a tetraorganylfluorogermanate.

引用

页码：91 / 95

页数：5

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