SOME WELL CHARACTERIZED CHEMICAL REACTIVITIES OF BUCKMINSTERFULLERENE (C-60)

被引:33
作者
FAGAN, PJ
CHASE, B
CALABRESE, JC
DIXON, DA
HARLOW, R
KRUSIC, PJ
MATSUZAWA, N
TEBBE, FN
THORN, DL
WASSERMAN, E
机构
[1] Central Research and Development Department, E.I. du Pont de Nemours, Co., Inc., Wilmington, DE 19880-0328
关键词
FULLERENE; REACTIVITY; RAMAN SPECTROSCOPY; METALATION; HALOGENATION; FREE RADICALS; ESR;
D O I
10.1016/0008-6223(92)90063-3
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The metalation, halogenation, and free radical addition chemistry of C60 is described. Vibrational spectroscopy is a useful tool in assigning the structures of the products. Several underlying principles emerge for C60 chemistry, some of which are supported by molecular orbital calculations.
引用
收藏
页码:1213 / 1226
页数:14
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