THE QUESTION OF DISPERSIVE KINETICS FOR THE INITIAL PHASE OF CHARGE SEPARATION IN BACTERIAL REACTION CENTERS

被引：62

作者：

SMALL, GJ

HAYES, JM

SILBEY, RJ

机构：

[1] IOWA STATE UNIV SCI & TECHNOL,DEPT CHEM,AMES,IA 50011

[2] MIT,DEPT CHEM,CAMBRIDGE,MA 02139

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1992年 / 96卷 / 19期

关键词：

D O I：

10.1021/j100198a005

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Recently, femtosecond time domain data have raised the possibility that the kinetics of the initial phase of charge separation could be dispersive due to the glasslike structural heterogeneity of proteins. Guided by spectral hole burning data, we have derived simple theoretical rate expressions which allow the question posed in the title to be explored.

引用

页码：7499 / 7501

页数：3

共 27 条

[21] MAGNITUDE AND DIRECTION OF THE CHANGE IN DIPOLE-MOMENT ASSOCIATED WITH EXCITATION OF THE PRIMARY ELECTRON-DONOR IN RHODOPSEUDOMONAS-SPHAEROIDES REACTION CENTERS [J].