STRUCTURE AND DYNAMICS OF LANTHANIDE(III) COMPLEXES OF THE BIS(PROPYLAMIDE) OF DIETHYLENETRIAMINEPENTAACETIC ACID IN AQUEOUS-SOLUTION

被引：32

作者：

GERALDES, CFGC ^{[1
]}

URBANO, AM ^{[1
]}

ALPOIM, MC ^{[1
]}

HOEFNAGEL, MA ^{[1
]}

PETERS, JA ^{[1
]}

机构：

[1] DELFT UNIV TECHNOL,ORGAN CHEM LAB,2628 BL DELFT,NETHERLANDS

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 09期

关键词：

D O I：

10.1039/c39910000656

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

NMR shift and relaxation measurements show that the lanthanide(III) complexes of the bis(propylamide) of diethylenetriaminepentaacetic acid (H3L) occur in at least eight isomeric forms, in which the metal ion is coordinated by a water molecule and the octadentate chelated organic ligand.

引用

页码：656 / 658

页数：3

共 15 条

[1] HYDRATION OF COMPLEXONE COMPLEXES OF LANTHANIDE CATIONS [J].

ALSAADI, BM ;

ROSSOTTI, FJC ;

WILLIAMS, RJP .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1980, (11) :2151-2154

[2]

ALSAADI BM, 1980, J CHEM SOC DA, P214

[3]

DWEK RA, 1973, NUCLEAR MAGNETIC RES

[4]

GERALDES CFG, 1988, MAGNET RESON MED, V8, P181

[5] SOLUTION STRUCTURE AND DYNAMICS OF LANTHANIDE(III) COMPLEXES OF DIETHYLENETRIAMINEPENTAACETATE - A TWO-DIMENSIONAL NMR ANALYSIS [J].

JENKINS, BG ;

LAUFFER, RB .

INORGANIC CHEMISTRY, 1988, 27 (26) :4730-4738

[6] GADOLINIUM COMPLEXATION BY A NEW DTPA AMIDE LIGAND - AMIDE OXYGEN COORDINATION [J].

KONINGS, MS ;

DOW, WC ;

LOVE, DB ;

RAYMOND, KN ;

QUAY, SC ;

ROCKLAGE, SM .

INORGANIC CHEMISTRY, 1990, 29 (08) :1488-1491

[7] PARAMAGNETIC METAL-COMPLEXES AS WATER PROTON RELAXATION AGENTS FOR NMR IMAGING - THEORY AND DESIGN [J].

LAUFFER, RB .

CHEMICAL REVIEWS, 1987, 87 (05) :901-927

[8]

Martell A.E., 1977, CRITICAL STABILITY C, V3

[9]

Martell A. E., 1982, CRITICAL STABILITY C, V5

[10]

MCLAUGHLIN AC, 1973, J MAGN RESON, V9, P296, DOI 10.1016/0022-2364(73)90046-2

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