CO Tolerance Improvement of MEA Using Metal Thin Film by Sputtering Method in PEM Fuel Cell

被引:1
作者
Cho, Yong-Hun [1 ]
Yoo, Sung Jong
Cho, Yoon-Hwan
Park, Hyun-Seo
Sung, Yung-Eun
机构
[1] Seoul Natl Univ, Sch Chem & Biol Engn, Seoul 151744, South Korea
来源
JOURNAL OF THE KOREAN ELECTROCHEMICAL SOCIETY | 2007年 / 10卷 / 04期
关键词
Polymer electrolyte membrane fuel cell (PEMFC); Membrane electrode assembly (MEA); CO tolerance; Sputtering system; Air injection;
D O I
10.5229/JKES.2007.10.4.279
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
When reformer for fuel cell is used, CO in hydrogen gas leads to a seriously decreased membrane electrode assembly (MEA) performance by catalyst poisoning. The effect of CO on performance of modified MEA by sputtering method is studied in this paper. The experimental results show that sputtered Pt and Ru thin film improve a single cell performance of MEA and sputtered metal thin film has a CO tolerance. The air injection process on anode show improved CO tolerance test result. Moreover, Pt, Ru and PtRu thin film by sputtering had influence on the CO tolerance with air injection process.
引用
收藏
页码:279 / 282
页数:4
相关论文
共 12 条
[1]   HYDROGEN-PRODUCTION BY STEAM REFORMING OF METHANOL FOR POLYMER ELECTROLYTE FUEL-CELLS [J].
AMPHLETT, JC ;
CREBER, KAM ;
DAVIS, JM ;
MANN, RF ;
PEPPLEY, BA ;
STOKES, DM .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 1994, 19 (02) :131-137
[2]  
Barir F., 2005, PEM FUEL CELLS THEOR
[3]   SOLID POLYMER FUEL-CELLS - AN ALTERNATIVE TO BATTERIES IN ELECTRIC VEHICLES - AN OVERVIEW [J].
BILLINGS, RE ;
SANCHEZ, M .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 1995, 20 (07) :521-529
[4]   Effect of platinum amount in carbon supported platinum catalyst on performance of polymer electrolyte membrane fuel cell [J].
Cho, Yong-Hun ;
Park, Hyun-Seo ;
Cho, Yoon-Hwan ;
Jung, Dae-Sik ;
Park, Hee-Young ;
Sung, Yung-Eun .
JOURNAL OF POWER SOURCES, 2007, 172 (01) :89-93
[5]   Pd-based PdPt(19:1)/C electrocatalyst as an electrode in PEM fuel cell [J].
Cho, Yong-Hun ;
Choi, Baeck ;
Cho, Yoon-Hwan ;
Park, Hyun-Seo ;
Sung, Yung-Eun .
ELECTROCHEMISTRY COMMUNICATIONS, 2007, 9 (03) :378-381
[6]   Reaction network of steam reforming of ethanol over Ni-based catalysts [J].
Fatsikostas, AN ;
Verykios, XE .
JOURNAL OF CATALYSIS, 2004, 225 (02) :439-452
[7]   Synthesis and characterization of novel acid-base polymer blends for application in membrane fuel cells [J].
Kerres, J ;
Ullrich, A ;
Meier, F ;
Häring, T .
SOLID STATE IONICS, 1999, 125 (1-4) :243-249
[8]  
LAMINIE J, 2000, FUEL CELL SYSTEM EXP
[9]  
Park H.-S., ELECTROCHIM IN PRESS
[10]  
Rakass S., 2003, J POWER SOURCES, V124, P432