5 ''-(4-Chlorobenzylidene)-1 '-(4-chlorophenyl)-1 ''-methyl-1 ',2 ',3 ',5 ',6 ',7 ',8 ',8a '-octahydrodispiro[acenaphthylene-1,3 '-indolizine-2 ',3 ''-piperidine]-2,4''(1H)-dione

被引:0
作者
Suresh, J. [1 ]
Nagalakshmi, R. A. [1 ]
Kumar, R. Ranjith [2 ]
Sivakumar, S. [2 ]
Lakshman, P. L. Nilantha [3 ]
机构
[1] Madura Coll, Dept Phys, Madurai 625011, Tamil Nadu, India
[2] Madurai Kamaraj Univ, Sch Chem, Dept Organ Chem, Madurai 625021, Tamil Nadu, India
[3] Univ Ruhuna, Dept Food Sci & Technol, Kamburupitiya 81100, Sri Lanka
关键词
data-to-parameter ratio = 18.8; mean ω(C-C) = 0.003 Å; R factor = 0.046; single-crystal X-ray study; T = 293 K; wR factor = 0.113;
D O I
10.1107/S160053681204545X
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, C37H32Cl2N2O2, the pyridinone ring adopts a twisted half-chair conformation. The fused pyrrolidine and piperidine rings of the octahydroindolizine unit exhibit envelope (with the C atom bound to the C atom bearing the chlorobenzene ring being the flap atom) and chair conformations, respectively. The dihedral angle between the chlorobenzene rings is 84.03 (1)degrees. In the crystal, C-H center dot center dot center dot pi interactions lead to supramolecular chains along [101] that assemble in the ac plane. Connections along the b axis are of the type Cl center dot center dot center dot Cl [3.4065 (8)angstrom].
引用
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页码:O3315 / +
页数:12
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