STEREOCOMPLEXATION OF POLY(METHYLMETHACRYLATES) IN MONOLAYERS AT THE AIR-WATER-INTERFACE

被引：0
作者：
BRINKHUIS, RHG
SCHOUTEN, AJ
机构：
[1] Laboratory of Polymer Chemistry, University of Groningen, Groningen, 9747 AG
来源：
MAKROMOLEKULARE CHEMIE-MACROMOLECULAR SYMPOSIA | 1991年 / 46卷
关键词：
D O I：
10.1002/masy.19910460148
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
When mixtures of isotactic and syndiotactic PMMA are spread on the air water interface from a non-complexing solvent, a pressure induced transition can be observed, that is identified as a stereocomplexation between the two stereoregular components in the mixture, similar to bulk or solution processes. Analogous to the monolayer crystallization of isotactic PMMA, double helical structures are formed that can be transferred to solid substrates forming oriented thin films.
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页码：341 / 345
页数：5
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