ELECTROGENERATED CHEMILUMINESCENCE .54. ELECTROGENERATED CHEMILUMINESCENCE OF RUTHENIUM(II) 4,4'-DIPHENYL-2,2'-BIPYRIDINE AND RUTHENIUM(II) 4,7-DIPHENYL-1,10-PHENANTHROLINE SYSTEMS IN AQUEOUS AND ACETONITRILE SOLUTIONS

被引：176
作者：
MCCORD, P
BARD, AJ
机构：
[1] Department of Chemistry and Biochemistry, The University of Texas at Austin, Austin
来源：
JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1991年 / 318卷 / 1-2期
基金：
美国国家科学基金会;
关键词：
D O I：
10.1016/0022-0728(91)85296-2
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
The electrogenerated chemiluminescence (ECL) of Ru(dp-bpy)3(2+) (dp-bpy = 4,4'-diphenyl-2,2'-bipyridine) and Ru(dp-phen)3(2+) (dp-phen = 4,7-diphenyl-1,10-phenanthroline) in acetonitrile and aqueous solutions was studied. The diphenyl-substituted compounds produced a more intense emission than the nonsubstituted Ru(bpy)3(2+) in acetonitrile. The ECL efficiencies, phi(ECL), of Ru(dp-bpy)3(2+) and Ru(dp-phen)3(2+) were estimated as 14% and 24% respectively. Similar results were obtained in aqueous solutions.
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页码：91 / 99
页数：9
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