HIGH-PRESSURE REACTOR AND CELL FOR ELECTRONIC AND INFRARED SPECTRAL STUDIES

被引：14

作者：

BALLINTINE, TA

SCHMULBACH, CD

机构：

[1] Department of Chemistry, Biochemistry Southern Illinois University, Carbondale

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 164卷 / 03期

关键词：

D O I：

10.1016/S0022-328X(00)81700-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An easily constructed, simply operated, high pressure reactor and ultraviolet-visible/infrared cell is described. The apparatus is designed for spectral studies of the interaction of transition metal complexes and small gaseous molecules in the liquid phase.Elevated pressures of the reacting gases are limited to those obtained with commercial bottled gases. An example of the utility of the apparatus is provided in the detection of an unstable ti(III) carbonyl, TiCl3(CO)(PEt3)2, by high pressure infrared spectroscopy. © 1979.

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页码：381 / 390

页数：10

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