SYNTHESIS OF TRANS,TRANS-ALPHA-FARNESENE

被引：42

作者：

BRIEGER, G

NESTRICK, TJ

MCKENNA, C

机构：

[1] Department of Chemistry, Oakland University, Rochester, Michigan

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1969年 / 34卷 / 12期

关键词：

D O I：

10.1021/jo01264a011

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The stereospecific preparation of tran,trans-α-farnesene by rhodium chloride catalyzed isomerization of trans-β-farnesene is reported. In addition, conjugated isomers, probably allofamesenes, are formed. The KHSO4- catalyzed dehydration of nerolidol has been investigated, yielding products identified as α- and β-farnesene, β-bisabolene, and δ-bisabolene. The base-catalyzed dehydration of farnesol has been reinvestigated. Only β-farnesene is formed, along with a mixture of C44 hydrocarbons identified as 2,6,10-trimethylundeca-2,4,9-triene and 2,6,10-trimethylundeca-1,5,9-triene. © 1969, American Chemical Society. All rights reserved.

引用

页码：3789 / &

共 21 条

[1] THERMAL DECARBOXYLATION OF UNSATURATED ACIDS [J].