PALLADIUM DIHALIDE COMPLEXES WITH D,L-ETHIONINE

被引：8

作者：

GUO, ZJ

FREGONA, D

FARAGLIA, G

SITRAN, S

机构：

[1] CNR,IST CHIM & TECNOL RADIOELEMENTI,CORSO STATI UNITI,I-35020 PADUA,ITALY

[2] UNIV PADUA,DIPARTIMENTO CHIM INORGAN MET ORGAN & ANALIT,I-35131 PADUA,ITALY

来源：

JOURNAL OF COORDINATION CHEMISTRY | 1993年 / 28卷 / 3-4期

关键词：

D; L-ETHIONINE; DIMETHYL-4-PYRONE; PALLADIUM COMPLEXES; SYNTHESIS; NMR;

D O I：

10.1080/00958979308037099

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

By reaction of palladium halides with D,L-ethionine (D,L-EthH; molar ratio 1:1) in dichloromethane solutions containing an excess of 2,6-dimethyl-4H-pyran-4-one (DMP) [Pd(D,L-EthH)X2] (X=Cl, Br or 1) complexes have been isolated. When the solvent was benzene [Pd(DL-EthH)X2].DMP adducts were obtained in which the DMP molecule does not bind to the metal. The complexes have been characterized by infrared and nmr (H-1 and C-13) Spectroscopy and by thermogravimetric measurements (TG, DTG and DTA). The importance of DMP in determining the reaction course is discussed.

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页码：209 / 216

页数：8

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