FORMATION OF CYCLIC AMIDINIUMIODIDES AND AMIDINIUMPOLYIODIDES FROM 1,3,5-TRIMETHYL-HEXAHYDRO-1,3,5-TRIAZINE AND IODINE

被引：4
|
作者：
STEGEMANN, H [1 ]
OPREA, A [1 ]
TEBBE, KF [1 ]
机构：
[1] UNIV COLOGNE,INST ANORGAN CHEM,W-5000 COLOGNE,GERMANY
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1995年 / 621卷 / 05期
关键词：
1,3,5-TRIMETHYL-TETRAHYDRO-1,3,5-TRIAZINIUM-IODIDE; 1,3,5-TRIMETHYL-TETRAHYDRO-1,3,5-TRIAZINIUM-TRIIODIDE 1,3,5-TRIMETHYL-TETRAHYDRO-1,3,5-TRIAZINIUM-PENTAIODIDE; IODINE; POLYIODIDE; CRYSTAL STRUCTURE;
D O I：
10.1002/zaac.19956210528
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of 1,3,5-trimethyl-hexahydro-1,3,5-triazine (CH3NCH2)(3) with iodine in the molar ratio (CH3NCH2)(3):I-2=2:1 gives the new compound 1,3,5-trimethyl-tetrahydro-1,3,5-triazinium-iodide C6H14N3I. This iodide adds one mole I-2 and forms 1,3,5-trimethyl-tetrahydro-1,3,5-triazinium-triiodide C6H14N3I3. The crystal structure analysis shows a cation, in which two methyl groups and five ring atoms are planar arranged. The third methyl group stands axial to the ring. 1,3,5-Trimethyl-tetrahydro-1,3,5-triazinium-pentaiodide is formed by adding a further mole I-2.
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收藏
页码：871 / 876
页数：6
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