N-(2-Carboxyethyl)-2,5-dideoxy-2,5imino-D-mannonic acid [(3R, 4R, 5R)1-( 2-carboxyethyl)-3,4-dihydroxy5- hydroxymethyl-L-proline]

被引：1
|
作者：
Edgeley, David S. [1 ]
Fernando Martinez, R. [2 ]
Jenkinson, Sarah F. [2 ]
Nash, Robert J. [3 ]
Fleet, George W. J. [2 ]
Thompson, Amber L. [1 ]
机构：
[1] Univ Oxford, Dept Chem Crystallog, Chem Res Lab, Oxford OX1 3TA, England
[2] Univ Oxford, Dept Organ Chem, Chem Res Lab, Oxford OX1 3TA, England
[3] Phytoquest Ltd, IBERS, Aberystwyth SY23 3EB, Ceredigion, Wales
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷
关键词：
D O I：
10.1107/S1600536812037488
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The absolute stereochemistry of the title compound, C9H15NO7, was determined from the use of d-glucuronolactone as the starting material. The compound crystallizes as the zwitterion. The five-membered ring adopts an envelope conformation with the-CH2OH-substituted C atom forming the flap. An intramolecular N-H center dot center dot center dot O hydrogen-bond occurs. In the crystal, the compound exists as a three-dimensional OH center dot center dot center dot O intermolecular hydrogen-bonded network with each molecule acting as a donor and acceptor for four hydrogen bonds.
引用
收藏
页码：O2865 / +
页数：8
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