NOVEL STEREOSELECTIVE PREPARATION AND CONFORMATIONAL-ANALYSIS OF FURANOSE-TYPE PHOSPHONO SUGAR C-GLYCOSIDES

被引：6

作者：

YABUI, A

YAMASHITA, M

OSHIKAWA, T

HANAYA, T

YAMAMOTO, H

机构：

[1] SHIZUOKA UNIV, FAC ENGN, DEPT APPL CHEM, HAMAMATSU, SHIZUOKA 432, JAPAN

[2] OKAYAMA UNIV, FAC SCI, DEPT CHEM, OKAYAMA 700, JAPAN

来源：

CHEMISTRY LETTERS | 1993年 / 01期

关键词：

D O I：

10.1246/cl.1993.93

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Treatment of 1-alkoxy-3-phospholene 1-oxide with lithium diisopropylamide followed by novel stereoselective C-alkylation with alkyl halides afforded 2-alkyl- and 2-benzyloxymethyl-3-phospholene 1-oxides, which were subjected to osmium (VIII) oxide-catalyzed diastereoselective cis-dihydroxylation to give new C-glycoside derivatives of furanose-type phosphono sugars, with twist conformation.

引用

收藏

页码：93 / 96

页数：4

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