Synthesis, molecular structure and Hirshfeld surface analysis of (4-methoxyphenyl)[2-(methylsulfanyl)thiopnen-3-yl]methanone

被引：0
|
作者：
Nagaraju, S. [1 ]
Sridhar, M. A. [1 ]
Kumara, C. S. Pradeepa [2 ]
Sadashiva, M. P. [2 ]
Lakshminarayana, B. N. [3 ]
Lokanath, N. K. [4 ]
机构：
[1] Univ Mysore, Dept Studies Phys, Mysore, Karnataka, India
[2] Univ Mysore, Dept Studies Chem, Mysuru, Karnataka, India
[3] Adichuchanagiri Inst Technol, Dept Studies Phys, Chikkamagaluru, Karnataka, India
[4] Univ Mysore, Dept Studies Phys, Mysuru, Karnataka, India
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2018年 / 74卷
关键词：
crystal structure; thiophene; Hirschfeld surface;
D O I：
10.1107/S2056989018016043
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, C13H12O2S2, crystallizes in the triclinic space group P (1) over bar. The molecular structure is substantially twisted, with a dihedral angle of 43.70 (2)degrees between the 2-(methylsulfanyl)thiophene and 4-methoxyphenyl rings. In the crystal, molecules are linked through C-H center dot center dot center dot O interactions and form a bifurcated layer stacking along the b-axis direction and enclosing R-2(2)(10) ring motifs. The phenyl rings are involved in pi-pi interactions with a centroid-centroid separation of 3.760 (2) angstrom. The Hirshfeld surfaces were studied and the contributions of the various intermolecular interactions were quantified.
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收藏
页码：1800 / +
页数：8
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