SYNTHESIS AND REACTIONS OF ARENE RUTHENIUM COMPLEXES CONTAINING NITROGEN-DONOR LIGANDS - CRYSTAL-STRUCTURE OF (P-CYMENE)2RU2CL2(N3)2

被引：40

作者：

BATES, RS ^{[1
]}

BEGLEY, MJ ^{[1
]}

WRIGHT, AH ^{[1
]}

机构：

[1] UNIV NOTTINGHAM,DEPT CHEM,NOTTINGHAM NG7 2RD,ENGLAND

来源：

POLYHEDRON | 1990年 / 9卷 / 08期

关键词：

D O I：

10.1016/S0277-5387(00)81303-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A range of nitrogen bases have been reacted with [(arene)RuCl2]2 complexes. The reaction with simple amines to give monomeric addition compounds (arene)RuCl2NR3 has been made rapid and quantitative using ultrasound. Steric factors predominate in determining the extent of the reactions. Trimethylsilylazide has been found to be a particularly suitable source of the azide ligand, generating the new dimer [(arene)Ru(μ-N3)Cl]2 which has been structurally characterized. This complex has been shown to undergo dimer cleavage and halide loss reactions. © 1990.

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页码：1113 / 1118

页数：6

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