SYNTHESIS OF ORGANOPALLADIUM(IV) COMPLEXES BY HALOGEN EXCHANGE, AND THE STRUCTURE OF THE AZIDOPALLADIUM(II) COMPLEX FORMED ON REDUCTIVE ELIMINATION OF ETHANE FROM PD(N3)ME2(CH2PH)(BPY)

被引：10

作者：

CANTY, AJ ^{[1
]}

TRAILL, PR ^{[1
]}

SKELTON, BW ^{[1
]}

WHITE, AH ^{[1
]}

机构：

[1] UNIV WESTERN AUSTRALIA,DEPT PHYS & INORGAN CHEM,NEDLANDS,WA 6009,AUSTRALIA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 402卷 / 02期

基金：

澳大利亚研究理事会;

关键词：

D O I：

10.1016/0022-328X(91)83076-G

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new route to organopalladium(IV) complexes is described, involving replacement of bromine in the 2,2'-bipyridyl complex PdBrMe2(CH2Ph)(bpy), by other halogen or pseudohalogen groups. H-1 NMR studies of the decomposition of PdXMe2(CH2Ph)(bpy) in warm (CD3)2CO indicate that a selectivity in reductive elimination of alkanes occurs, to give ethane (X = Br, N3, NCS), or a mixture of ethane and ethylbenzene in ca. 9/1 ratio (X = F, Cl, I). The reductive elimination product azido(2,2'-bipyridyl)benzylpalladium(II) has been characterized by X-ray crystallography.

引用

页码：C33 / C36

页数：4

共 19 条

[1]

AYE KT, 1989, ORGANOMETALLICS, V8, P1518

[2] SYNTHESIS OF THE STABLE ORGANOPALLADIUM(IV) COMPLEXES [FAC-PDRME2(TRIPOD)]X AND SELECTIVE REDUCTIVE ELIMINATION OF ETHANE FROM (ETA-1-ALLYL)PALLADIUM(IV) COMPLEXES TO FORM (ETA-3-ALLYL)PALLADIUM(II) COMPLEXES [J].

BROWN, DG ;

BYERS, PK ;

CANTY, AJ .

ORGANOMETALLICS, 1990, 9 (04) :1231-1235

[3]

Burmeister J.L., 1966, COORDIN CHEM REV, V1, P205, DOI [10.1016/S0010-8545(00)80174-5, DOI 10.1016/S0010-8545(00)80174-5]

[4] SYNTHESIS, REACTIVITY, AND STRUCTURAL STUDIES IN TRIMETHYLPALLADIUM(IV) CHEMISTRY, INCLUDING PDIME3(BPY) AND [PDME3((PZ)3CH)]+, [PTME3((PZ)3CH]+ [J].

BYERS, PK ;

CANTY, AJ ;

SKELTON, BW ;

WHITE, AH .

ORGANOMETALLICS, 1990, 9 (03) :826-832

[5] SYNTHESIS OF METHYLPALLADIUM(II) CATIONIC COMPLEXES FROM [PDME(SME2)(MU-I)]2 - CRYSTAL-STRUCTURE OF [PDME(BPY)(GAMMA-PIC)]BF4 [J].

BYERS, PK ;

CANTY, AJ ;

SKELTON, BW ;

WHITE, AH .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 393 (02) :299-306

[6] SYNTHESIS AND DECOMPOSITION OF NEUTRAL PALLADIUM(IV) COMPLEXES CONTAINING FAC-PDME2R GROUPS, INCLUDING REDUCTIVE ELIMINATION BY ETA-1-PROPENYLPALLADIUM(IV) COMPLEXES TO FORM ETA-3-PROPENYLPALLADIUM(II) SPECIES [J].

BYERS, PK ;

CANTY, AJ ;

TRAILL, PR ;

WATSON, AA .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 390 (03) :399-407

[7] CONVENIENT SYNTHETIC ROUTES TO MEDPII, ME2PDII, AND ME3PDIV COMPLEXES - THE CRYSTAL-STRUCTURE OF THE MEDPDII COMPLEX [MEPD(2,2'-BIPYRIDYL)(GAMMA-PICOLINE)]BF4 [J].

BYERS, PK ;

CANTY, AJ ;

SKELTON, BW ;

WHITE, AH .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1987, 336 (03) :C55-C60

[8] THE OXIDATIVE ADDITION OF IODOMETHANE TO [PDME2(2,2'-BIPYRIDYL)] AND THE X-RAY STRUCTURE OF THE ORGANOPALLADIUM(IV) PRODUCT FAC-[PDME3(2,2'-BIPYRIDYL)L] [J].

BYERS, PK ;

CANTY, AJ ;

SKELTON, BW ;

WHITE, AH .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (23) :1722-1724

[9] REACTIVITY AND MECHANISM IN OXIDATIVE ADDITION TO PALLADIUM(II) AND REDUCTIVE ELIMINATION FROM PALLADIUM(IV) AND AN ESTIMATE OF THE PALLADIUM-METHYL BOND-ENERGY [J].

BYERS, PK ;

CANTY, AJ ;

CRESPO, M ;

PUDDEPHATT, RJ ;

SCOTT, JD .

ORGANOMETALLICS, 1988, 7 (06) :1363-1367

[10]

BYERS PK, 1990, IN PRESS ORGANOMETAL, V9

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