PALLADIUM CATALYZED STEREOSPECIFIC CYCLIZATION OF HYDROXY EPOXIDES - STEREOCONTROLLED SYNTHESIS OF CIS-2-ALKENYL AND TRANS-2-ALKENYL-3-HYDROXYTETRAHYDROPYRANS

被引：94

作者：

SUZUKI, T ^{[1
]}

SATO, O ^{[1
]}

HIRAMA, M ^{[1
]}

机构：

[1] TOHOKU UNIV,FAC SCI,DEPT CHEM,SENDAI,MIYAGI 980,JAPAN

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 33期

关键词：

D O I：

10.1016/S0040-4039(00)97722-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Stereospecific constructions of the cis- and trans-2-alkenyl-3-hydroxytetrahydropyrans have been achieved by the one-pot procedure of desilylation-palladium catalyzed cyclization of the silyl ethers of ω-hydroxy trans- and cis-γ,°-epoxy-α,β-unsaturated esters, respectively. © 1990.

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页码：4747 / 4750

页数：4

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