COORDINATION OF 2,2'-BIIMIDAZOLE WITH IRON, COBALT, NICKEL AND COPPER

被引：54
作者：
ABUSHAMLEH, AS
GOODWIN, HA
机构：
[1] School of Chemistry, University of New South Wales, Kensington, NSW, 2033
来源：
AUSTRALIAN JOURNAL OF CHEMISTRY | 1979年 / 32卷 / 03期
关键词：
D O I：
10.1071/CH9790513
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Complexes of 2, 2′-biimidazole with bivalent iron, cobalt, nickel and copper, and trivalent iron are described. The ligand produces a relatively weak field and all complexes are high-spin and markedly less stable than corresponding complexes of 2, 2'-bipyridine or 2-(2-pyridy1)imidazole. Inner complexes, M(L-H)2, derived from the monoanion of biimidazole are also described. The complexes are characterized by magnetic and spectral data. © 1979 Australian Journal of Chemistry. All rights reserved.
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页码：513 / 518
页数：6
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共 32 条
  • [1] ANTSYSHKINA AS, 1962, DOKL AKAD NAUK SSSR+, V143, P105
  • [2] CRYSTAL STRUCTURE OF IODIBOS-(2,2'-BIPYRIDYL)COPPER(II) IODIDE
    BARCLAY, GA
    KENNARD, CHL
    HOSKINS, BF
    [J]. JOURNAL OF THE CHEMICAL SOCIETY, 1963, (DEC): : 5691 - &
  • [3] CARBONYL-COMPLEXES OF CHROMIUM, MOLYBDENUM AND TUNGSTEN WITH 2,2'-BIIMIDAZOL AND 5,5'-BITRIAZOL
    BECK, W
    GOTZFRIED, F
    RIEDERER, M
    [J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1976, 423 (02): : 97 - 102
  • [4] BIDENTATE CHELATE COMPOUNDS .3. METAL COMPLEXES OF SOME PYRIDYL-IMIDAZOLE DERIVATIVES
    CHISWELL, B
    LIONS, F
    MORRIS, BS
    [J]. INORGANIC CHEMISTRY, 1964, 3 (01) : 110 - &
  • [5] MOSSBAUER STUDIES OF IRON ORGANOMETALLIC COMPLEXES .3. OCTAHEDRAL COMPLEXES
    COLLINS, RL
    PETTIT, R
    BAKER, WA
    [J]. JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1966, 28 (04): : 1001 - &
  • [6] SOME NITRATO-AMINE NICKEL(2) COMPOUNDS WITH MONODENTATE AND BIDENTATE NITRATE IONS
    CURTIS, NF
    CURTIS, YM
    [J]. INORGANIC CHEMISTRY, 1965, 4 (06) : 804 - &
  • [7] DEBUS H, 1858, LIEBIGS ANN CHEM, V107, P199, DOI DOI 10.1002/JLAC.18581070209
  • [8] Dosser R. J., 1972, J CHEM SOC DA, P611
  • [9] MAGNETIC AND MOSSBAUER STUDIES OF A 5T-1A EQUILIBRIUM IN SOME IRON(2)-2-(2-PYRIDYL)IMIDAZOLE COMPLEXES
    DOSSER, RJ
    EILBECK, WJ
    UNDERHIL.AE
    EDWARDS, PR
    JOHNSON, CE
    [J]. JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1969, (05): : 810 - &
  • [10] COBALT(II) COMPLEXES OF 2-(2'-PYRIDYL)IMIDAZOLE
    DOSSER, RJ
    UNDERHIL.AE
    [J]. JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1974, 36 (06): : 1239 - 1242
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