COORDINATION OF 2,2'-BIIMIDAZOLE WITH IRON, COBALT, NICKEL AND COPPER

被引：54
作者：
ABUSHAMLEH, AS
GOODWIN, HA
机构：
[1] School of Chemistry, University of New South Wales, Kensington, NSW, 2033
来源：
AUSTRALIAN JOURNAL OF CHEMISTRY | 1979年 / 32卷 / 03期
关键词：
D O I：
10.1071/CH9790513
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Complexes of 2, 2′-biimidazole with bivalent iron, cobalt, nickel and copper, and trivalent iron are described. The ligand produces a relatively weak field and all complexes are high-spin and markedly less stable than corresponding complexes of 2, 2'-bipyridine or 2-(2-pyridy1)imidazole. Inner complexes, M(L-H)2, derived from the monoanion of biimidazole are also described. The complexes are characterized by magnetic and spectral data. © 1979 Australian Journal of Chemistry. All rights reserved.
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页码：513 / 518
页数：6
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