1ST STABLE DERIVATIVE OF 7-STANNANORBORNANE AND ITS THERMOLYSIS

被引：29

作者：

GRUGEL, C

NEUMANN, WP

SCHRIEWER, M

机构：

[1] Universität Dortmund, Dortmund, D-4600, Otto-Hahn-Strasse

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1979年 / 18卷 / 07期

关键词：

D O I：

10.1002/anie.197905431

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Free dimethylstannanediyl (“dimethylstannylene”) 2—to be regarded as truly free because of its synthesis—has been generated by thermolysis of the adduct 1 which is stable at −30°C. A concerted mechanism is proposed to account for the formation of 2. (Figure Presented.) Copyright © 1979 by Verlag Chemie, GmbH, Germany

引用

页码：543 / 544

页数：2

共 7 条

[1]

GASPAR PP, 1978, REACTIVE INTERMEDIAT

[2]

GRUGEL C, 1978, TETRAHEDRON LETT, P2847

[3] DIORGANOSTANNYLENES .3. FORMATION OF DIMETHYLSTANNYLENE FROM 1,1-DIMETHYL-2,3,4,5-TETRAPHENYL-1-STANNACYCLOPENTADIENE AND ACETYLENES [J].