KINETICS, MECHANISMS, AND CATALYSIS OF OXYGEN ATOM TRANSFER-REACTIONS OF S-OXIDE AND PYRIDINE N-OXIDE SUBSTRATES WITH MOLYBDENUM(IV,VI) COMPLEXES - RELEVANCE TO MOLYBDOENZYMES

被引:84
作者
CARADONNA, JP [1 ]
REDDY, PR [1 ]
HOLM, RH [1 ]
机构
[1] HARVARD UNIV,DEPT CHEM,CAMBRIDGE,MA 02138
关键词
D O I
10.1021/ja00215a022
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
引用
收藏
页码:2139 / 2144
页数:6
相关论文
共 46 条
[1]   PROPERTIES OF THE PROSTHETIC GROUPS OF RABBIT LIVER ALDEHYDE OXIDASE - A COMPARISON OF MOLYBDENUM HYDROXYLASE ENZYMES [J].
BARBER, MJ ;
COUGHLAN, MP ;
RAJAGOPALAN, KV ;
SIEGEL, LM .
BIOCHEMISTRY, 1982, 21 (15) :3561-3568
[2]   HETEROCYCLIC FLUORINE COMPOUNDS .5. FLUOROPYRIDINE OXIDES AND FLUOROQUINOLINE N-OXIDES [J].
BELLAS, M ;
SUSCHITZKY, H .
JOURNAL OF THE CHEMICAL SOCIETY, 1963, (AUG) :4007-&
[3]   A MODEL FOR THE ACTIVE-SITES OF OXO-TRANSFER MOLYBDOENZYMES - REACTIVITY, KINETICS, AND CATALYSIS [J].
BERG, JM ;
HOLM, RH .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (04) :925-932
[4]   A MODEL FOR THE ACTIVE-SITES OF OXO-TRANSFER MOLYBDOENZYMES - SYNTHESIS, STRUCTURE, AND PROPERTIES [J].
BERG, JM ;
HOLM, RH .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (04) :917-925
[5]   SYNTHETIC APPROACH TO THE MONONUCLEAR ACTIVE-SITES OF MOLYBDOENZYMES - CATALYTIC OXYGEN ATOM TRANSFER-REACTIONS BY OXOMOLYBDENUM(IV,VI) COMPLEXES WITH SATURATION KINETICS AND WITHOUT MOLYBDENUM(V) DIMER FORMATION [J].
BERG, JM ;
HOLM, RH .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (10) :3035-3036
[6]  
BERNASCONI CF, 1986, TECHNIQUES CHEM, V6, pCH12
[7]   MOLYBDENUM(IV) OXO COMPLEXES WITH OXYGEN, NITROGEN, AND SULFUR LIGANDS - SYNTHESES AND ELECTROCHEMICAL STUDIES [J].
BOYD, IW ;
SPENCE, JT .
INORGANIC CHEMISTRY, 1982, 21 (04) :1602-1606
[8]  
Bray R C, 1980, Adv Enzymol Relat Areas Mol Biol, V51, P107
[9]   STUDIES BY ELECTRON-PARAMAGNETIC-RESONANCE SPECTROSCOPY OF THE MOLYBDENUM CENTER OF ALDEHYDE OXIDASE [J].
BRAY, RC ;
GEORGE, GN ;
GUTTERIDGE, S ;
NORLANDER, L ;
STELL, JGP ;
STUBLEY, C .
BIOCHEMICAL JOURNAL, 1982, 203 (01) :263-267
[10]   ELECTRON-PARAMAGNETIC-RESONANCE STUDIES USING PRE-STEADY-STATE KINETICS AND SUBSTITUTION WITH STABLE ISOTOPES ON THE MECHANISM OF ACTION OF MOLYBDOENZYMES [J].
BRAY, RC ;
GEORGE, GN .
BIOCHEMICAL SOCIETY TRANSACTIONS, 1985, 13 (03) :560-567