1,3-DIPOLAR CYCLOADDITION BETWEEN ETHYL TRIFLUOROACETOACETATE AND N-(BENZYLIDENE)METHYLAMINE N-OXIDE

被引：15

作者：

BEGUE, JP

BONNETDELPON, D

LEQUEUX, T

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1991年 / 11期

关键词：

D O I：

10.1039/p19910002888

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The 1,3-dipolar cycloaddition between ethyl trifluoroacetoacetate and N-(benzylidene)methylamine N-oxide, performed in boiling toluene, leads regio- and stereo-selectively to an isoxazolidine, while the corresponding ethyl acetoacetate is found to be unreactive under the same conditions. On the other hand, alpha-trifluoromethylstyrene behaves as alpha-methylstyrene and affords two diastereoisomeric trifluoromethyl-substituted cycloadducts.

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页码：2888 / 2889

页数：2

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