TRIPHENYLENE-BASED DISCOTIC-LIQUID-CRYSTALLINE POLYMERS - A UNIVERSAL, RATIONAL SYNTHESIS

被引：115

作者：

BODEN, N ^{[1
]}

BUSHBY, RJ ^{[1
]}

CAMMIDGE, AN ^{[1
]}

机构：

[1] UNIV LEEDS,SCH CHEM,LEEDS LS2 9JT,W YORKSHIRE,ENGLAND

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1995年 / 117卷 / 03期

关键词：

D O I：

10.1021/ja00108a009

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A simple, regiospecific synthesis of main-chain, triphenylene-based discotic-liquid-crystalline polymers is described in which the key step is the assembly of the triphenylene nucleus through the oxidative coupling of phenyl and biphenyl residues. Hence, treatment of a mixture of 3,3'-bis(hexyloxy)-4,4'-dimethoxybiphenyl and 1,2-bis(hexyloxy)benzene with ferric chloride in dichloromethane followed by a reductive, methanol workup gives 2,7-dimethoxy-3,6,10,11-tetrakis(hexyloxy)tr 7. The 2,7-linked main-chain polymer 8 is produced by demethylation and condensation with 1,11-dibromoundecane, has average molecular weight 24 000, and D-h mesophase range of 98-118 degrees C. The 3,6- and 2,3-linked polymers were prepared in a similar manner.

引用

页码：924 / 927

页数：4

共 11 条

[1] A QUICK-AND-EASY ROUTE TO UNSYMMETRICALLY SUBSTITUTED DERIVATIVES OF TRIPHENYLENE - PREPARATION OF POLYMERIC DISCOTIC LIQUID-CRYSTALS [J].