MULTIPLET SPLITTING OF CORE-ELECTRON BINDING ENERGIES IN TRANSITION-METAL IONS

被引：280

作者：

FADLEY, CS

SHIRLEY, DA

FREEMAN, AJ

BAGUS, PS

MALLOW, JV

机构：

[1] Department of Chemistry, Lawrence Radiation Laboratory, University of California, Berkeley

[2] Department of Physics, Northwestern University, Evanston

[3] IBM Research Laboratory, San Jose

[4] Magnetic Theory Group, Department of Physics, Northwestern University, Evanston

来源：

PHYSICAL REVIEW LETTERS | 1969年 / 23卷 / 24期

关键词：

D O I：

10.1103/PhysRevLett.23.1397

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

X-ray photoelectron spectra indicate core-electron binding-energy splittings of 6 eV for the 3s levels in MnF2, MnO, and FeF3, and less pronounced effects on the 3s levels in MnO2 and Fe metal. These splittings are considerably reduced from free-ion predictions but agree well with calculations for Mn in a cluster environment. The 3p multiplet splittings are shown to behave in a quantitatively different fashion. © 1969 The American Physical Society.

引用

页码：1397 / &

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