O-H AND O-D STRETCHING VIBRATIONS IN ISOTOPICALLY DILUTE HDO MOLECULES IN SOME SOLID HYDRATES

被引：128
作者：
BERGLUND, B
LINDGREN, J
TEGENFELDT, J
机构：
[1] Institute of Chemistry. University of Uppsala, Box 531
来源：
JOURNAL OF MOLECULAR STRUCTURE | 1978年 / 43卷 / 02期
关键词：
D O I：
10.1016/0022-2860(78)80004-0
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Vibrational frequencies vOH and vOD have been measured for isotopically-dilute HDO molecules in eleven solid hydrates at 90 K. The results have been used to prepare a plot of the ratio vOH/vOD versus vOH. The ratios fall on a smooth curve and decrease with decreasing frequencies vOH. The anharmonicity constants ωexe have been estimated. They were found to increase with decreasing vOH. © 1978.
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页码：169 / 177
页数：9
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