APPLICATION OF SCALED-PARTICLE THEORY TO THE PROBLEM OF MICELLIZATION

被引：11

作者：

NANDI, N ^{[1
]}

BASUMALLICK, IN ^{[1
]}

机构：

[1] VISVA BHARATI UNIV,DEPT CHEM,SANTINIKETAN 731235,W BENGAL,INDIA

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1990年 / 94卷 / 06期

关键词：

D O I：

10.1021/j100369a058

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The cavity-forming free energies of micellization (ΔG°cav) for a series of sodium alkyl (C8-C14) sulfates have been computed according to scaled-particle theory (SPT). Other conventional components of free energies (ΔG°i) of micellization for these detergents have also been calculated by use of previously developed models. Analysis of ΔG°cav indicates that cavity-forming free energies play an important role in the process of micellization. © 1990 American Chemical Society.

引用

页码：2537 / 2540

页数：4

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