TRANSITION-METAL-(CARBOXYLATO)TRIHYDROBORATE COMPLEXES - COPPER AND SILVER TRIPHENYLPHOSPHINE COMPLEXES OF H3BCO2R-(R = H, CH3, C2H5)

被引：28

作者：

BOMMER, JC ^{[1
]}

MORSE, KW ^{[1
]}

机构：

[1] UTAH STATE UNIV,DEPT CHEM & BIOCHEM,LOGAN,UT 84322

来源：

INORGANIC CHEMISTRY | 1979年 / 18卷 / 03期

关键词：

D O I：

10.1021/ic50193a001

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis and characterization of some copper and silver triphenylphosphine complexes of the (carboxylato)trihydroborate derivatives. H3BCO2R-(R=H, CH3, C2H5) are reported. Isolated are stable crystalline complexes of composition (Ph3P)nMH3BCO2R (n=2, 3; M=Cu, R=C2H5, CH3, H; M=Ag, R=C2H5, H). Results of spectral (IR, NMR), osmometric, and conductivity studies are discussed in terms of the molecular structures of the complexes; possible factors influencing the bidentate or monodentate mode of coordination by the anion are set forth. © 1979, American Chemical Society. All rights reserved.

引用

页码：531 / 538

页数：8

共 30 条

[1]

ATWOOD JL, 1977, J CHEM SOC CHEM COMM, P593

[2] INTRAMOLECULAR EXCHANGE AND THERMAL DECOUPLING IN B3H8-COMPOUNDS [J].