CHEMICAL-TRANSFORMATIONS ON THE SURFACE OF [60]FULLERENE - SYNTHESIS OF [60]FULLERENO[1',2'/4,5]OXAZOLIDIN-2-ONE

被引：55

作者：

BANKS, MR

CADOGAN, JIG

GOSNEY, I

HODGSON, PKG

LANGRIDGESMITH, PRR

MILLAR, JRA

TAYLOR, AT

机构：

[1] UNIV LONDON IMPERIAL COLL SCI TECHNOL & MED,DEPT CHEM,LONDON SW7 2AY,ENGLAND

[2] BP INT LTD,RES & ENGN CTR,SUNBURY TW16 7LN,MIDDX,ENGLAND

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 48期

关键词：

D O I：

10.1016/0040-4039(94)88429-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Base-induced alpha-elimination from substituted O-4-nitrophenylsulfonylhydroxamic acids has been used as a mild source of nitrenes for capture by [60]fullerene; rearrangment of the resulting [60]fullereno[1',2':2,3]aziridine bearing a N-ethoxycarbonyl grouping under the influence of phenol/chlorotrimethylsilane results in the quantitative formation of the title compound which can be cleaved to yield 1-hydroxy-2-N-methylamino[60]fullerene.

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页码：9067 / 9070

页数：4

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