NOVEL PROCESSES FOR STEREOSELECTIVE ORGANIC-SYNTHESIS

被引：22
作者：
MOLANDER, GA
MAUTNER, K
机构：
[1] Department of Chemistry and Biochemistry, University of Colorado, Boulder, Colorado
来源：
PURE AND APPLIED CHEMISTRY | 1990年 / 62卷 / 04期
关键词：
D O I：
10.1351/pac199062040707
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The application of oxiranyl anions in organic synthesis represents a unique means to introduce the epoxide functional group into organic molecules. Unlike simple oxidation procedures, use of these nucleophiles increases molecular complexity in the carbon skeleton at the same time new functionality is created. The generation and utility of trialkylsilyl-substituted oxiranyl anions is highlighted in this paper. © 1990, IUPAC.
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页码：707 / 712
页数：6
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