CARBOXYLATION OF PROPANE WITH CO TO BUTYRIC ACIDS BY PD(II)/CU(II) BASED CATALYSTS

被引：21

作者：

MIYATA, T

NAKATA, K

YAMAOKA, Y

TANIGUCHI, Y

TAKAKI, K

FUJIWARA, Y

机构：

来源：

CHEMISTRY LETTERS | 1993年 / 06期

关键词：

D O I：

10.1246/cl.1993.1005

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Propane reacts with CO leading to isobutyric and butyric acids in good yields by the Pd(OAc)2/Cu(OAc)2/K2S2O8 catalyst system via C-H bond activation. It is essential to use more than unity of the Cu(OAc)2/Pd(OAc)2 ratio to attain high yield.

引用

页码：1005 / 1008

页数：4

共 5 条

[1]

FUJIWARA Y, 1990, CHEMTECH, P636

[2]

MIYATA T, UNPUB

[3] PALLADIUM CATALYZED CARBOXYLATION OF CYCLOHEXANE WITH CARBON-MONOXIDE [J].

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TAKAKI, K ;

FUJIWARA, Y .

CHEMISTRY LETTERS, 1991, (08) :1437-1438

[4] TRANSITION-METAL CATALYZED ACETIC-ACID SYNTHESIS FROM METHANE AND CO [J].

NISHIGUCHI, T ;

NAKATA, K ;

TAKAKI, K ;

FUJIWARA, Y .

CHEMISTRY LETTERS, 1992, (07) :1141-1142

[5] PD-CATALYZED REGIOSELECTIVE AND STEREOSELECTIVE CARBOXYLATION OF CYCLOALKANES WITH CO [J].

SATOH, K ;

WATANABE, J ;

TAKAKI, K ;

FUJIWARA, Y .

CHEMISTRY LETTERS, 1991, (08) :1433-1436

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