ANALYSIS OF PROPOSED AROMATIC PRECURSORS OF HOP BITTER ACIDS

被引：22

作者：

FUNG, SY ^{[1
]}

BRUSSEE, J ^{[1
]}

VANDERHOEVEN, RAM ^{[1
]}

NIESSEN, WMA ^{[1
]}

SCHEFFER, JJC ^{[1
]}

VERPOORTE, R ^{[1
]}

机构：

[1] LEIDEN UNIV,LEIDEN AMSTERDAM CTR DRUG RES,DIV PHARMACOGNOSY,GORLAEUS LABS,2300 RA LEIDEN,NETHERLANDS

来源：

JOURNAL OF NATURAL PRODUCTS | 1994年 / 57卷 / 04期

关键词：

D O I：

10.1021/np50106a003

中图分类号：

Q94 [植物学];

学科分类号：

071001 ;

摘要：

Four proposed precursors of hop bitter acids, 2-acyl-1,3,5-benzenetriol and 2-acyl-4-(3-methyl-2-butenyl)-1,3,5-benzenetriol (acyl=2-methylpropanoyl or 3-methylbutanoyl), were synthesized (compounds 7-10). Tlc, hplc and gc systems were developed for the analysis of these compounds in the presence of the hop bitter acids 1-6. All four precursors were found to be present in cone extracts of several hop cultivars.

引用

页码：452 / 459

页数：8

共 15 条

[1] SYNTHESIS OF THE MAMMEA COUMARINS .1. THE COUMARINS OF THE MAMMEA A-SERIES, B-SERIES, AND C-SERIES
CROMBIE, L
JONES, RCF
PALMER, CJ
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1987, (02): : 317 - 331
[2] BIOSYNTHESIS OFHOP BITTER PRINCIPLES .8. MONOPRENYLATED ACYLPHLOROGLUCINOLS
DRAWERT, F
BEIER, J
[J]. PHYTOCHEMISTRY, 1976, 15 (11) : 1695 - 1696
[3] Drawert F., 1974, Chromatographia, V7, P273, DOI 10.1007/BF02290543
[4] FORMATION AND FURTHER REACTION OF ACYL PRECURSORS OF HOP RESINS
DRAWERT, F
BEIER, J
[J]. PHYTOCHEMISTRY, 1974, 13 (10) : 2149 - 2155
[5] HANSEL R, 1986, DTSCH APOTH ZTG, V126, P2347
[6] HIGHLY PURIFIED FLAVANONE SYNTHASE FROM PARSLEY CATALYZES THE FORMATION OF NARINGENIN CHALCONE
HELLER, W
HAHLBROCK, K
[J]. ARCHIVES OF BIOCHEMISTRY AND BIOPHYSICS, 1980, 200 (02) : 617 - 619
[7] MIZOBUCHI S, 1985, REPORTS RES LAB KIRI, V28, P39
[8] RIEDL W, 1954, LIEBIGS ANN CHEM, V585, P38
[9] UBER HOPFENBITTERSTOFFE .12. ZUR KENNTNIS DES 4-DESOXY-HUMULONS
RIEDL, W
HUBNER, H
[J]. CHEMISCHE BERICHTE-RECUEIL, 1957, 90 (12): : 2870 - 2876
[10] RIEDL W, 1951, BRAUWISSENSCHAFT, V6, P81

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