ORGANOMETALLIC COMPLEX COMPOUNDS .4. SEPARATION OF STERIC AND ELECTRONIC EFFECTS IN THE REACTION ENTHALPIES OF ASSOCIATION OF PHOSPHORUS LIGANDS

被引：34

作者：

SCHENKLUHN, H ^{[1
]}

SCHEIDT, W ^{[1
]}

WEIMANN, B ^{[1
]}

ZAHRES, M ^{[1
]}

机构：

[1] MAX PLANCK INST COAL RES,D-4330 MULHEIM,FED REP GER

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1979年 / 18卷 / 05期

关键词：

D O I：

10.1002/anie.197904011

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An understanding of the directing influence of Lewis bases in homogeneous transition metal catalysis is brought nearer by data characterizing the metal‐ligand bond. The enthalpy of reaction of 1 with L was measured for 22 phosphorus ligands L and resolved into “steric” and “electronic” components. (Figure Presented.) Copyright © 1979 by Verlag Chemie, GmbH, Germany

引用

页码：401 / 402

页数：2

共 7 条

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HEIMBACH P, UNPUBLISHED

[2] EINFACHES DIFFERENTIAL-CALORIMETER ZUR KINETISCHEN UNTERSUCHUNG VON LOSUNGSREAKTIONEN ZWISCHEN -140 UND +90 DEGREES C [J].