MOLECULAR GRAPHICS AND ASYMMETRIC CATALYSIS

被引：6
|
作者：
BOSNICH, B
机构：
[1] Department of Chemistry, The University of Chicago, Chicago, Illinois 60637
来源：
PURE AND APPLIED CHEMISTRY | 1990年 / 62卷 / 06期
关键词：
D O I：
10.1351/pac199062061131
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Molecular graphics and Van der Waals minimizations are used to analyze the steric interactions of the enantioselective step of asymmetric catalytic hydrogenation of amino acid precursors using chiral bidentate phosphine rhodium (I) complexes. It is concluded that, of the eight possible hydrogenation paths, only two, one for each diastereomer, are allowed because of severe steric interactions in the other six paths. © 1990 IUPAC
引用
收藏
页码：1131 / 1134
页数：4
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