ADSORPTION OF TRIBLOCK COPOLYMERS ON ROUGH SURFACES

被引：23

作者：

BALAZS, AC ^{[1
]}

HUANG, KL ^{[1
]}

LANTMAN, CW ^{[1
]}

机构：

[1] BAYER USA INC,MOBAY CORP,PITTSBURGH,PA 15205

来源：

MACROMOLECULES | 1990年 / 23卷 / 21期

关键词：

D O I：

10.1021/ma00223a023

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

We examine the adsorption of ABA triblocks in solution onto a rough, corrugated surface. The solution is assumed to be a good solvent for the B block and a bad solvent for the A segments. Solvent incompatibility drives the A blocks to adsorb onto the nearest interface. We find that, under favorable conditions, the A moieties bind to the ridges of the bumpy surface and the B segments span the wells that lie between two ridges. Consequently, the adsorption of triblocks acts to smooth or planarize a rough surface. We discuss how chain length and the value of XBS, the interaction energy between the B block and the surface, affect the efficiency of this process. © 1990, American Chemical Society. All rights reserved.

引用

页码：4641 / 4647

页数：7

共 17 条

[1] COMPUTER-SIMULATION FOR STRUCTURE FORMATION FROM SELF-ASSEMBLING POLYMERS [J].