ELECTRONIC EFFECTS AND MECHANISTIC FEATURES IN THE REARRANGEMENT-DISPLACEMENT REACTIONS OF ARYL(CHLOROMETHYL)DIPHENYLSILANES WITH FLUORIDE-ION

被引：11

作者：

APRAHAMIAN, SL ^{[1
]}

SHECHTER, H ^{[1
]}

机构：

[1] OHIO STATE UNIV,DEPT CHEM,COLUMBUS,OH 43210

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 08期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0040-4039(00)88733-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

At 25°C aryl migrations from negatively-charged pentacoordinate silicon correlate with the abilities of the rearranging groups to bear negative charge, but at lower temperatures the migrations become less dependent on electron-withdrawing stabilization. © 1990.

引用

收藏

页码：1089 / 1092

页数：4

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