STEREOCHEMISTRY OF ORGANOMERCURY COMPOUNDS .2. A REDETERMINATION OF STRUCTURE OF MERCURY(2) CYANIDE BY NEUTRON DIFFRACTION

被引：57
作者：
SECCOMBE, RC
KENNARD, CHL
机构：
[1] Department of Chemistry, University of Queensland, Brisbane
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1969年 / 18卷 / 02期
关键词：
D O I：
10.1016/S0022-328X(00)85392-9
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The crystal structure of mercury(II) cyanide, Hg(CN)2, has been determined using three dimensional neutron diffraction data. The compound crystallizes out in a tetragonal unit cell, space group I42d; cell dimensions, a = 9.643, c = 8.88 ». There are eight molecules per unit cell. Interatomic distances and angles are: Hg-C, 2.015(3); C-N, 1.137(3); non bonding Hg-N, 2.742(3) »; C-Hg-C, 175.0(2)°; Hg-C-N, 177.0(3)°. © 1969.
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页码：243 / &
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