A reversal of the sign of the W-183-F-19 spin-spin coupling constant in octahedral tungsten(VI) derivatives

被引：4

作者：

McFarlane, W.

Noble, A. ^{[1
]}

Winfield, J. ^{[1
]}

机构：

[1] Univ Glasgow, Dept Chem, Glasgow W2, Lanark, Scotland

来源：

CHEMICAL PHYSICS LETTERS | 1970年 / 6卷 / 05期

关键词：

D O I：

10.1016/0009-2614(70)85218-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In contrast with the behaviour of many coupling constants. (1)J(W-183-F-19) can change sign without an accompanying change in the valence of tungsten: the two W-F coupling constants have the same sign in MeOWF5 and related compounds, but they have opposite signs in the WOF5- anion.

引用

页码：547 / 548

页数：2

共 12 条

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