EFFECTS OF SECONDARY INTERACTIONS ON THE STEREOCHEMICAL OUTCOME OF RHODIUM(II) CARBOXYLATE CATALYZED CYCLOPROPANATION OF OLEFINS

被引：23
作者：
DEMONCEAU, A
NOELS, AF
HUBERT, AJ
机构：
[1] STATE UNIV LIEGE,MACROMOLEC CHEM & ORGAN CATALYSIS LAB,B-4000 LIEGE,BELGIUM
[2] STATE UNIV LIEGE,ORGAN SYNTH & CATALYSIS LAB,B-4000 LIEGE,BELGIUM
来源：
TETRAHEDRON | 1990年 / 46卷 / 11期
关键词：
D O I：
10.1016/S0040-4020(01)90524-1
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
In cyclopropanation reactions of olefins catalysed by various dirhodium(II) tetracarboxylates, it is shown that besides the well-recognized electronic and steric effets, secondary interactions between the carbenoid complex and the substrate largely determine the stereoselectivity of the cyclopropanes. © 1990.
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页码：3889 / 3896
页数：8
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