A NOVEL REACTION OF COORDINATED VINYLIDENES - COUPLING WITH HYDROGEN-SULFIDE TO GIVE A ETA(1)-THIOALDEHYDE

被引：33

作者：

BIANCHINI, C

GLENDENNING, L

PERUZZINI, M

ROMEROSA, A

ZANOBINI, F

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 19期

关键词：

D O I：

10.1039/c39940002219

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The Ru-II fragment [(PN P)RuCl2] assists the coupling of phenylacetylene with H2S to give 2-phenylethanethial [PNP = CH3CH2CH2N(CH(2)CH(2)PPh(2))(2)] in a reaction that is initiated by alk-1-yne to vinylidene tautomerism at ruthenium, followed by electrophilic attack of H2S on the vinylidene ligand; P-phenylethanethial is recovered as either eta(1)-S-ligand or endo-6-benzyl-1-thiabicyclo[2.2.1]hept-3-ene ligand, and the latter molecule is formed via a stereoselective Diels-Alder reaction between cyclopentadiene and the eta(1)-2-phenylethanethial complex.

引用

收藏

页码：2219 / 2220

页数：2

相关论文

共 30 条

[1] REGIOSELECTIVE AND STEREOSELECTIVE DIMERIZATION OF 1-ALKYNES CATALYZED BY AN OS(II) COMPLEX [J].

BARBARO, P ;

BIANCHINI, C ;

PERUZZINI, M ;

POLO, A ;

ZANOBINI, F ;

FREDIANI, P .

INORGANICA CHIMICA ACTA, 1994, 220 (1-2) :5-19

[2] SURPRISING DIFFERENCES IN THE CYCLOADDITION REACTIONS OF CUMULENES AND HETEROCUMULENES TO VINYLIDENETITANOCENE - FORMATION OF 4-MEMBERED OR 5-MEMBERED TITANACYCLES [J].

BECKHAUS, R ;

STRAUSS, I ;

WAGNER, T ;

KIPROF, P .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1993, 32 (02) :264-266

[3] SYNTHESIS, REDOX PROPERTIES, AND REACTIVITY OF A NOVEL FAMILY OF ELECTRON-RICH VINYLIDENE AND VINYLPHOSPHONIUM COMPLEXES OF RHODIUM(I) [J].

BIANCHINI, C ;

MELI, A ;

PERUZZINI, M ;

ZANOBINI, F ;

ZANELLO, P .

ORGANOMETALLICS, 1990, 9 (01) :241-250

[4]

BIANCHINI C, 1992, GAZZ CHIM ITAL, V122, P461

[5] A RU(II) ENYNYL COMPLEX MEDIATES THE CATALYTIC DIMERIZATION OF 1-ALKYNES TO Z-1,4-DISUBSTITUTED ENYNES [J].

BIANCHINI, C ;

PERUZZINI, M ;

ZANOBINI, F ;

FREDIANI, P ;

ALBINATI, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (14) :5453-5454

[6] REACTIONS OF THE CATIONIC IRON VINYLIDENE COMPOUND [FE(ETA-C5H5)(CO)(PPH3)(C=CH2)]+BF4-WITH O-H, N-H, S-H, CL-H, AND C=C BONDS [J].

BOLANDLUSSIER, BE ;

HUGHES, RP .

ORGANOMETALLICS, 1982, 1 (04) :635-639

[7] ORGANOMETALLIC CHEMISTRY OF VINYLIDENE AND RELATED UNSATURATED CARBENES [J].

BRUCE, MI .

CHEMICAL REVIEWS, 1991, 91 (02) :197-257

[8] CYCLOPENTADIENYL-RUTHENIUM AND CYCLOPENTADIENYL-OSMIUM CHEMISTRY - SOME REACTIONS OF SUBSTITUTED VINYLIDENE COMPLEXES [J].

BRUCE, MI ;

SWINCER, AG ;

WALLIS, RC .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1979, 171 (01) :C5-C8

[9] CYCLOPENTADIENYL-RUTHENIUM AND CYCLOPENTADIENYL-OSMIUM CHEMISTRY - CLEAVAGE OF TETRACYANOETHYLENE UNDER MILD CONDITIONS - X-RAY CRYSTAL-STRUCTURES OF [RU(ETA-3-C(CN)2CPHC=C(CN)2)(PPH3)(ETA-C5H5)] AND [RU(C[=C(CN)2]CPH=C(CN)2)-(CNBUT)(PPH3)(ETA-C5H5)] [J].

BRUCE, MI ;

RODGERS, JR ;

SNOW, MR ;

SWINCER, AG .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1981, (06) :271-272

[10]

FERACIN S, 1992, HELV CHIM ACTA, V75, P1035