ADIABATIC RATE PROCESSES IN CONDENSED MEDIA

被引：10

作者：

FAIN, B

机构：

[1] Department of Chemistry, Tel-Aviv University, Tel Aviv

来源：

CHEMICAL PHYSICS LETTERS | 1979年 / 67卷 / 2-3期

关键词：

D O I：

10.1016/0009-2614(79)85160-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A model appropriate for the description of adiabatic nuclear group transfer processes in condensed media is developed. At low temperatures, the model is isomorphous to a well explored theoretical model with two intersecting electronic energy hypersurfaces. At high temperatures the rate equations describing the overcoming of the barrier between the potential wells by the excitations of the surrounding media are derived. © 1979.

引用

页码：267 / 272

页数：6

共 13 条

[1]

[Anonymous], 1966, ADV ELECTROCH EL ENG

[2]

CHILD M, 1974, J MOL SPECTROSC, V52, P280

[3] ENERGY GAP LAW FOR RADIATIONLESS TRANSITIONS IN LARGE MOLECULES [J].