EVIDENCE FOR CYCLOPROPENE FORMATION IN THE REACTIONS OF 4,4-DIMETHYL-4-SILACYCLOHEXADIENYLIDENE

被引：14

作者：

COLEMAN, B

JONES, M

机构：

[1] Department of Chemistry, Princeton University Princeton

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 168卷 / 03期

关键词：

D O I：

10.1016/S0022-328X(00)83220-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In the reactions of 4,4-dimethylcyclohexadienylidene no evidence for cyclopropene formation has been found. By contrast, 4,4-dimethyl-4-silacyclohexadienylidene yields a product on reaction with butadiene that is best rationalized by intramolecular cyclopropene formation. © 1979.

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页码：393 / 401

页数：9

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